Synthesis and structure of [Et2Bi(OAr)]∞(Ar = C6F5, Ph): a new inorganic chain polymer
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 1021-1022
- https://doi.org/10.1039/c39920001021
Abstract
Triethylbismuth reacts slowly with HOAr (Ar = C6F5, Ph) in refluxing toluene to yield the compounds [BiEt2OAr]∞ which are shown by single crystal X-ray diffraction to exist as chiral chain polymers in which bridging alkoxides join Et2Bi groups containing a stereoactive lone pair of electrons.Keywords
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