Colloid-Polymer Mixtures at Triple Coexistence: Kinetic Maps from Free-Energy Landscapes
- 9 August 1999
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 83 (6) , 1239-1242
- https://doi.org/10.1103/physrevlett.83.1239
Abstract
We have studied the kinetics of phase separation in a colloid-polymer mixture. The evolution of initially homogeneous samples as they separate into coexisting colloidal gas, liquid, and crystal phases was investigated by time-lapse video recording. Distinct kinetic regimes were found, the existence and character of which are interpreted in terms of the “free energy landscape” of the system.Keywords
This publication has 9 references indexed in Scilit:
- Phase separation, aggregation and gelation in colloid-polymer mixtures and related systemsCurrent Opinion in Colloid & Interface Science, 1998
- The shape of the van der Waals loop and universal critical amplitude ratiosJournal of Physics A: General Physics, 1998
- Relationship of phase diagrams and surfaces of new phase nucleation ratesThe Journal of Chemical Physics, 1998
- Effect of the Steric Stabilizing Layer on the Phase Behavior and Rheology of Small Polystyrene Latex Dispersions Induced by Changes to the Concentration of Nonadsorbing HydroxyethylcelluloseLangmuir, 1997
- Phase behavior of a model colloid-polymer mixturePhysical Review E, 1995
- Prediction of an expanded-to-condensed transition in colloidal crystalsPhysical Review Letters, 1994
- Phase Behaviour of Colloid + Polymer MixturesEurophysics Letters, 1992
- Liquid-crystalline and microemulsion phase behavior in alcohol-free Aerosol-OT/oil/brine systemsThe Journal of Physical Chemistry, 1987
- The Metastable Liquidus and Its Effect on the Crystallization of GlassJournal of the American Ceramic Society, 1969