The effects of chemically induced polarisation in the cage recombination products of the methyl radical
- 1 November 1973
- journal article
- Published by Wiley in Magnetic Resonance in Chemistry
- Vol. 5 (11) , 537-546
- https://doi.org/10.1002/mrc.1270051109
Abstract
A study of the CIDNP effects on methyl protons was carried out for the cage recombination products formed during the thermal decomposition reactions of peracetyls and peracetylcarbonates. The increase of both the cage recombination product yield and the enhancement of CIDNP on the CH3 protons is shown to be connected with the RCO2 radical lifetime, where R is an alkyl or alkoxy radical. A general theory of CIDNP is presented and the calculated data prove to be in satisfactory agreement with the experimental results.Keywords
This publication has 8 references indexed in Scilit:
- The chemical polarization of the proton spins in the 13C containing moleculesChemical Physics Letters, 1971
- Role of Diffusion-Controlled Reaction in Chemically Induced Nuclear Spin PolarizationThe Journal of Chemical Physics, 1970
- Theory of chemically induced nuclear spin polarization. V. Comparison of coupling reactions in singlet and triplet derived radical pairs and of radicals not generated in pairsJournal of the American Chemical Society, 1970
- Inducing Dynamic Nuclear Polarization in Chemical ReactionsSpectroscopy Letters, 1970
- Chemically induced dynamic nuclear polarization IIChemical Physics Letters, 1969
- Chemically induced nuclear spin polarization as a tool for determination of spin multiplicities of radical-pair precursorsJournal of the American Chemical Society, 1969
- A Treatment of Chemical Kinetics with Special Applicability to Diffusion Controlled ReactionsThe Journal of Chemical Physics, 1954
- Relaxation Effects in Nuclear Magnetic Resonance AbsorptionPhysical Review B, 1948