Supramolecular assembly of low-dimensional silver(i) architectures: testing the reliability of the self-complementary oxime⋯oxime hydrogen-bond interaction
- 17 July 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in CrystEngComm
- Vol. 4 (55) , 310-314
- https://doi.org/10.1039/b202303m
Abstract
The syntheses and crystal structure determinations of three new compounds, bis-[4′-[N-(4-pyridylmethylene)]aminoacetophenone oxime] silver(I) hexafluorophosphate hydrate, bis-[4′-[N-(4-pyridylmethylene)]aminoacetophenone oxime] silver(I) perchlorate hydrate, and bis-[3′-[N-(4-pyridylmethylene)]aminoacetophenone oxime] silver(I) hexafluorophosphate hydrate, demonstrate that the desired primary supramolecular synthon, the oxime⋯oxime dimer, is not disrupted despite extensive ligand modifications (through covalent synthesis) that increase the aromatic content and introduce an additional hydrogen-bond acceptor moiety.Keywords
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