C-alkylation reactions of phenylsulphonylnitromethane. A convenient new α-nitro-sulphone synthesis
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 287-288
- https://doi.org/10.1039/c39800000287
Abstract
Phenylsulphonylnitromethane (1) is C-alkylated by benzylic halides and primary alkyl iodides affording α-nitro-sulphones in 43–75% yield; α-nitro-sulphones (83–90% yield) are also obtained from the corresponding C-alkylation of allylic acetates in the presence of catalytic Pd(PPh3)4.Keywords
This publication has 0 references indexed in Scilit: