Kinetics of the reactions of NCO radicals with H2 and NO using laser photolysis–laser induced fluorescence
- 15 June 1985
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 82 (12) , 5485-5488
- https://doi.org/10.1063/1.448583
Abstract
Absolute rate constants for the reaction of NCO radicals with hydrogen (k6; T=592–913K) and nitric oxide (k7;T=294–538K) were measured using excimer laser photolysis‐laser induced fluorescence at 416.8 nm. The following Arrhenius expressions summarize the data: k6=1.43×10−11e(−9000±1500)/RT k7=1.69×10−11e(390±320)/RT cm3 molecule−1 s−1. The experimental technique and results are discussed, and the importance of these reactions to combustion chemistry is addressed.Keywords
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