Separation of structural isomers of tetra-tert-butylphthalocyaninatonickel(II)

Abstract
Tetra-tert-butylphthalocyaninatonickel is synthesized from phthalic anhydride as well as from phthalodinitrile and nickel chloride, whereby a mixture of four different structural isomers are obtained; two of these isomers, with C2v-and Cs-symmetry are isolated for the first time by HPLC and medium pressure liquid chromatography (MPLC) and characterized.

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