Effect of substituents on the stereoselectivity of the acid-catalysed hydrolysis of a series of aryloxirans. A new application of the Hammett equation
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 712-713
- https://doi.org/10.1039/c39740000712
Abstract
Correlation of the logarithms of the ratios of cis to trans diols formed in the acid-catalysed hydrolysis of 13 1-arylcyclohexene oxides with the σ+ constants indicates that there is a higher degree of carbocationic character in the transition state leading to the cis-product.Keywords
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