Determination of Ionic Partial Molar Volumes of Bolaform Electrolytes by Means of Sedimentation Potential Measurements
- 1 September 1988
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 61 (9) , 3315-3316
- https://doi.org/10.1246/bcsj.61.3315
Abstract
Sedimentation potentials (SP) and electrical conductivities have been measured in aqueous solutions of three kinds of bolaform electrolytes, [R3N–(CH2)n–NR3]Br2 where R stands for ethyl group and n is equal to 4, 6, and 10. Using the SP and conductivity data the partial molar volumes of the bolaform salts were divided into cationic and anionic parts. Two ionic sites of the bolaform electrolytes behave independently.Keywords
This publication has 4 references indexed in Scilit:
- Measurement of sedimentation potential and its application to the determination of individual ionic partial molar volumesThe Journal of Physical Chemistry, 1987
- Thermodynamics of bolaform electrolytes. IV. Enthalpies and partial molal heat capacities in H2O, D2O, and dimethylsulfoxideJournal of Solution Chemistry, 1975
- Thermodynamics of bolaform electrolytes. III. Partial and apparent molal volumes in H2O and D2OJournal of Solution Chemistry, 1974
- Thermodynamics of bolaform electrolytes. I. Heat capacities and enthalpies in H2O and D2OJournal of Solution Chemistry, 1973