DIFFUSION WITH MIGRATION IN THE DIFFUSE DOUBLE LAYER

1 April 1963

journal article
Published by Canadian Science Publishing in Canadian Journal of Chemistry

Vol. 41 (4) , 983-1006
https://doi.org/10.1139/v63-137

Abstract

The polarization characteristics of the concentration of the reactive species are discussed when the effects of migration in the diffuse layer are accounted for. A limiting case (ξ₀ → ∞) and some particular cases (|Z_i/Z| = 0, 1, 2, 3, 4) are derived both for attraction and repulsion in the double layer. Linear approximations (and conditions sufficient to validate these) are presented. Some general results which relate the functional forms of the transforms of the interfacial concentrations for the cases of attraction and repulsion are also pointed out.

Keywords

MIGRATION
POLARIZATION
FUNCTIONAL
DOUBLE LAYER
CONCENTRATIONS
INTERFACIAL
SUFFICIENT
ZI/Z

This publication has 1 reference indexed in Scilit:

FARADAIC RECTIFICATION AND ELECTRODE PROCESSES¹
The Journal of Physical Chemistry, 1960