Triple-point wetting of neon films

Abstract
High-resolution quartz microbalance measurements of Ne films on Ag show a continuous transition from incomplete to complete wetting. The wetting temperature is identical to the triple point Tt to within a few millikelvins. The frequency shift Δf0 corresponding to the maximum thickness at TTt follows a power law Δf0t1/n, with n’=2.39, at reduced temperatures 0.001<t<0.03. Frequency-pressure isotherms above Tt indicate higher-order terms in the thermodynamic potential. These terms can be quantitatively explained by a model of substrate-field-induced solidification. Similar isotherm shapes below Tt suggest that stratification occurs on both sides of the triple point.