Thiirenium ion as intermediate in unimolecular reactions of β-arylthiovinyl sulphonic esters
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 24,p. 1520-1521
- https://doi.org/10.1039/c29690001520
Abstract
The equilibration of the two ethylenic carbons and the stereospecificity observed in unimolecular reactions of β-arylthiovinyl sulphonates (I) are explained by the intermediacy of a thiirenium cation (III).Keywords
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