syn–anti-Stereoselection in the Diels–Alder reactions of 1,2,3,4,5-pentamethylcyclopentadiene
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 18,p. 1247-1248
- https://doi.org/10.1039/c39850001247
Abstract
Very similar syn-anti-adduct ratios were observed when 1,2,3,4,5-pentamethylcyclopentadiene reacted with a variety of (Z)-ethylenic dienophiles, suggesting that in the exo region the transition-state geometries are very similar.Keywords
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