Synthesis of β-ZrClN by Thermal Decomposition of Zirconium(IV) Amide Trichloride
- 1 August 1986
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 59 (8) , 2627-2628
- https://doi.org/10.1246/bcsj.59.2627
Abstract
The zirconium amide trichloride ZrCl3(NH2)·7NH3 was prepared by the reaction of ZrCl4 with liquid ammonia. On heating up to 600°C in flowing ammonia gas, the amide was efficiently converted into β-ZrClN, whereas under vacuum it was decomposed to a different product. The decomposition processes were followed by using a quartz spring balance.Keywords
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