An improved synthesis of 13-epi-steroids
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 18,p. 748
- https://doi.org/10.1039/c39750000748
Abstract
Treatment of oximes of 17-keto steroids with refluxing acetic anhydride and pyridine, and acid hydrolysis of the resulting enamides, constitutes an efficient route to 13-epi-17-keto-steroids; this observation is evidence that the former reaction proceeds by a freeradical pathway.Keywords
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