Nuclear magnetic resonance and electronic spectral studies of Carbonato‐ammine Cobalt(III) Complexes
- 1 July 1972
- journal article
- research article
- Published by Wiley in Zeitschrift für anorganische und allgemeine Chemie
- Vol. 391 (1) , 54-59
- https://doi.org/10.1002/zaac.19723910107
Abstract
A series of carbonato‐ammine cobalt(III) Complexes were prepared. The chemical shifts observed in 59Co n. m.r. in these complexes have been explained on the basis of the theory of GRIFFITH and ORGEL. The relative order of ligand field strength obtained from n. m.r. data is in good agreement with the optical data. The splittings of the bands the visible and near u.v. region were examined, and the various crystal field parameters (Dq′ B, Dt′) are discussed.Keywords
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