Some Observations on Linearity of Response with the Flame lonization Detector

Abstract
It has been observed that a logarithmic plot between integrated peak area and concentration of solute exists for at least two orders of magnitude above the line of linear response. This represents an additional useful area for quantitative measurement. A postulate involving overloading at the detector site occuring as a fixed concentration level within the detector will account for this type of observed response. Mathematical derivations are presented to support this postulate.

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