Perfluormethyl-Element-Liganden, XXIV Organozinnverbindungen als Reagenzien, III Spaltungsreaktionen der Element-Element-Bindung in Verbindungen des Typs RnE-ERm(R = CH3, CF3·E =P, As, Se, Te · n,m = 1, 2)/Perfluormethyl Element Ligands, XXIV ; Organotin Compounds as Reagents, III Cleavage Reactions of the Element-Element-Bond in Compounds of the Type RnE-ERm (R = CH3CF3; E = P, AS, S, Se, Te; n,m=1, 2)
Open Access
- 1 January 1981
- journal article
- research article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 36 (1) , 48-54
- https://doi.org/10.1515/znb-1981-0111
Abstract
A systematic study of the cleavage of element-element bonds in compounds of the type RnE-ERm (R = CH3, CF3; E = P, As, S, Se, Te; n,m = 1, 2) by the group IV A element hydrides Me3M′H (M′ = Si, Ge, Sn; Me - CH3) has been carried out. To evaluate the reaction pathway, for a number of compounds the attack of H2O, CH3OH, HBr and HI has been investigated. Possible reaction intermediates have been synthesized by independent routes and tested under comparable conditions.Keywords
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