Metal Insertion into C−C Bonds in Solution
- 1 April 1999
- journal article
- review article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 38 (7) , 870-883
- https://doi.org/10.1002/(sici)1521-3773(19990401)38:7<870::aid-anie870>3.0.co;2-3
Abstract
What kind of ligated metal center is necessary for insertion into the “hidden” C−C bond? How can one tune the metal center for C−C bond activation by variation of the steric and electronic properties of ligands? What are the possible mechanisms of C−C bond activation in various reaction systems? A systematic look at the available data on C−C bond activation in solution provides some answers to these questions.Keywords
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