Percolation-type growth of branched polymers near gelation threshold
- 1 May 1989
- journal article
- research article
- Published by Taylor & Francis in Contemporary Physics
- Vol. 30 (3) , 203-218
- https://doi.org/10.1080/00107518908222597
Abstract
We present experimental results to illustrate the percolation model, and use this model to describe the structure and mass distribution of clusters, the increase of the connectivity as the percolation threshold is approached, as well as transport properties of electrical percolating networks. We discuss results obtained from neutron and light scattering and from mechanical measurements. A good agreement between theory and experiment allows the growth of polymer clusters during the gelation process to be understood. Results obtained from mechanical measurements are quite similar to the behaviour of electrical properties of percolating networks, but are not yet understood completely.Keywords
This publication has 13 references indexed in Scilit:
- Frequency Dependence of Viscoelastic Properties of Branched Polymers near Gelation ThresholdEurophysics Letters, 1987
- Size and mass determination of clusters obtained by polycondensation near the gelation thresholdJournal de Physique, 1987
- Gelation and percolation : swelling effectJournal de Physique, 1986
- Mechanical measurements in the reaction bath during the polycondensation reaction, near the gelation thresholdMacromolecules, 1985
- Superconductivity exponents in two- and three-dimensional percolationPhysical Review B, 1984
- Dilution and polydispersity in branched polymersJournal de Physique Lettres, 1984
- Scaling theory of percolation clustersPhysics Reports, 1979
- Critical Behaviour of Conductivity and Dielectric Constant near the Metal‐Non‐Metal Transition ThresholdPhysica Status Solidi (b), 1976
- Gelation in concentrated critically branched polymer solutions. Percolation scaling theory of intramolecular bond cyclesJournal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1976
- On a relation between percolation theory and the elasticity of gelsJournal de Physique Lettres, 1976