SELECTIVE OXIDATION OF ALLYLIC METHYLS IN MEDIUM RING COMPOUNDS
- 5 December 1981
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 10 (12) , 1703-1706
- https://doi.org/10.1246/cl.1981.1703
Abstract
Allylic methyls in medium ring compounds were selectively oxidized to primary alcohols and αβ-unsaturated aldehydes by means of t-butylhydroperoxide and selenium dioxide supported on silica gel.This publication has 7 references indexed in Scilit:
- Conformational aspects of caryophyllene. Population of stable conformers and ring inversion barrier of trans cyclononene ring portionTetrahedron Letters, 1981
- Conformational studies on humulene by means of empirical force field calculations. Role of stable conformers of humulene in biosynthetic and chemical reactionsJournal of the American Chemical Society, 1980
- Allylic oxidation of olefins by catalytic and stoichiometric selenium dioxide with tert-butyl hydroperoxideJournal of the American Chemical Society, 1977
- Chemisorbed chromyl chloride as a selective oxidantThe Journal of Organic Chemistry, 1977
- Reduction of epoxides to olefins with low valent titaniumThe Journal of Organic Chemistry, 1975
- Dry ozonation. Method for stereoselective hydroxylation of saturated compounds on silica gelThe Journal of Organic Chemistry, 1975
- Mechanistic studies regarding the oxidation of alcohols by silver carbonate on celiteThe Journal of Organic Chemistry, 1974