Metal-assisted reactions: part 19. Burst kinetics in heterogeneous catalytic transfer hydrogenolysis
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 1069-1076
- https://doi.org/10.1039/p19870001069
Abstract
Arene formation by catalytic transfer hydrogenolysis of aryloxytetrazolyl ethers in the liquid-phase shows biphasic concentration-time curves which indicate rate-limiting dissociation of heterogeneous complexes between catalyst and one of the reaction products, a tetrazolone. A dependence of catalytic reaction rate on pH and following modifications made to the catalyst are reported also.Keywords
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