Boron Derivatives of Benzaldimines and Salicylaldimines
- 1 January 1979
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 9 (3) , 223-241
- https://doi.org/10.1080/00945717908057459
Abstract
Reactions of equimolar amounts of unsymmetrical monoisopropoxyboranes with N-substituted benzaldimines and salicylaldimines have been carried out in benzene as solvent. Most of the resulting benzaldimine derivatives are distillable liquids, whereas those of salicyl-aldimines are solids and appear to be resistant to hydrolysis. All of these have been characterized by elemental analyses, IR, 1H NMR and 11B NMR spectral studies and conductance measurements. Ebullioscopic determinations of molecular weights show that these compounds are monomeric.Keywords
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