Syntheses and X-ray crystal structures of lithium and chromium(II) complexes of the tri-t-butylmethoxide ligand
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 1438-1439
- https://doi.org/10.1039/c39830001438
Abstract
The syntheses and X-ray crystal structures of Li and CrII complexes of the tri-t-butylmethoxide ligand are described, these are [{Li(OCBut 3)(thf)}2] and [Cr(OCBut 3)2·LiCl(thf)2](thf = tetrahydrofuran); the latter compounds has a rare distorted T-shaped geometry at chromium and when dissolved in n-hexane gives LiCl and a complex that analyses as [Cr(OCBut 3)2(thf)2].Keywords
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