Alkylation of the sodium enolate of ethyl acetoacetate in dimethoxyethane. Leaving groups effect on rate and orientation

1 January 1974

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 10,p. 377-378
https://doi.org/10.1039/c39740000377

Abstract

There is no evident relationship between rate and the ratio of C- to O-alkylation products in the reaction of the sodium enolate of ethyl acetoacetate with EtI, EtBr, TsOEt, FSO₃Et, and CF₃SO₃Et in dimethoxyethane.

Keywords

SODIUM ENOLATE
ETHYL ACETOACETATE
ENOLATE OF ETHYL
ETBR
ETI
ORIENTATION
FSO3ET

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