THE STEREOSELECTIVE FORMATION OF THREONINE FROM cis- AND trans-1-α-METHYLBENZYL-2-METHOXYCARBONYL-3-METHYL AZIRIDINES
- 5 April 1979
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 8 (4) , 313-314
- https://doi.org/10.1246/cl.1979.313
Abstract
The reaction of methyl α,β-dibromobutyrate with α-methylbenzylamine resulted in the formation of cis- and trans-1-α-methylbenzyl-2-methoxycarbonyl-3-methyl aziridines(II and III), which were converted to threonine predominantly upon the hydrolytic ring opening of the aziridines.This publication has 5 references indexed in Scilit:
- S-2,3-d1carboxy-aziridine, a new metabolite from a Streptomyces.The Journal of Antibiotics, 1975
- Nuclear Magnetic Resonance Study of the Stereoisomeric 2-Oxazolidone and 2-Phenyl-2-oxazoline Derivatives of α-Amino-β-hydroxy AcidsBulletin of the Chemical Society of Japan, 1973
- Bildung, Ringspaltung und Isomerisierung von Äthylenimin‐carbonsäure‐(2)‐DerivatenEuropean Journal of Inorganic Chemistry, 1960
- Synthesis of Phenylalanine and 8-Phenylserine from Cinnamic Acid.Nippon kagaku zassi, 1957
- Stereochemistry of the β-Phenylserines: Improved Preparation of Allophenylserine1Journal of the American Chemical Society, 1953