The First Electron‐Donor‐Acceptor Paracyclophanes with Ferrocene NLO‐Phores: Synthesis, Absorption and Electrochemical Properties
- 1 May 1997
- journal article
- research article
- Published by Wiley in European Journal of Inorganic Chemistry
- Vol. 130 (5) , 581-584
- https://doi.org/10.1002/cber.19971300508
Abstract
As potential nonlinear optical material. 12‐nitro‐4,7‐bis(2‐ferrocenylvinyl)[2.2]paracyclophane (1) and 12‐nitro‐4,5,7,8‐tetrakis(2‐ferrocenylvinyl)[2.2]paracyclophane(2) have been synthesized by pd‐catalyzed coupling reactions of vinylferrocene with the precursor cyclophanes 9 and 13, respectively. The absorption and electrochemical properties of 1 and 2 are also described.Keywords
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- Design and Synthesis of Organic Molecular Compounds for Efficient Second-Harmonic GenerationPublished by Elsevier ,1987