Magnetic susceptibility of low-dimensional organic conductors with bis(ethylenedithio) tetrathiafulvalene: (BEDT-TTF)3(ClO4)2 and (BEDT-TTF)2ClO4(C2H3Cl3)0.5

Abstract
The magnetic susceptibilities, χ, have been measured for 2 two-dimensional metallic bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) perchlorate salts under slow or rapid cooling conditions. (BEDT-TTF)3(ClO4 )2 shows a semimetal-insulator transition due to a Peierls instability at 175 K which is independent of the cooling rate. (BEDT-TTF)2 ClO4(C2 H3 Cl3 )0.5 shows a semimetal-semimetal transition associated with nesting of a part of the Fermi surface at 25 K under slow cooling. Under rapid cooling this transition disappears. The dependence of the transition observed for χ on the cooling rate is confirmed by resistivity measurements. The properties and the origin of anomalies observed for χ with the two salts are discussed in connection with the motion of ethylene groups and C2 H3 Cl3 molecules.