Magnetic susceptibility of low-dimensional organic conductors with bis(ethylenedithio) tetrathiafulvalene: (BEDT-TTF( and (BEDT-TTF(
- 15 July 1987
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 36 (3) , 1457-1462
- https://doi.org/10.1103/physrevb.36.1457
Abstract
The magnetic susceptibilities, χ, have been measured for 2 two-dimensional metallic bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) perchlorate salts under slow or rapid cooling conditions. (BEDT-TTF( shows a semimetal-insulator transition due to a Peierls instability at 175 K which is independent of the cooling rate. (BEDT-TTF ( shows a semimetal-semimetal transition associated with nesting of a part of the Fermi surface at 25 K under slow cooling. Under rapid cooling this transition disappears. The dependence of the transition observed for χ on the cooling rate is confirmed by resistivity measurements. The properties and the origin of anomalies observed for χ with the two salts are discussed in connection with the motion of ethylene groups and molecules.
Keywords
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