Synthesis and crystal structures of the metallacyclopentane complexes (η⁵-cyclopentadienyl)(triphenylphosphine)(butane-1,4-diyl)cobalt(III) and (η⁵-pentamethylcyclopentadienyl)(triphenylphosphine)-(butane-1,4-diyl)iridium(III)

1 January 1977

journal article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 22,p. 811-812
https://doi.org/10.1039/c39770000811

Abstract

Reactions of (3) and (4) with the organomagnesium reagents (1) or (2) lead to the metallacyclopentane derivatives (5) and (6), respectively; the X-ray structures of these compounds are reported.

Keywords

CRYSTAL STRUCTURE

Synthesis and crystal structures of the metallacyclopentane complexes (η5-cyclopentadienyl)(triphenylphosphine)(butane-1,4-diyl)cobalt(III) and (η5-pentamethylcyclopentadienyl)(triphenylphosphine)-(butane-1,4-diyl)iridium(III)

Abstract

Keywords

Synthesis and crystal structures of the metallacyclopentane complexes (η⁵-cyclopentadienyl)(triphenylphosphine)(butane-1,4-diyl)cobalt(III) and (η⁵-pentamethylcyclopentadienyl)(triphenylphosphine)-(butane-1,4-diyl)iridium(III)