New Approximations to the Regular Solutions. I
- 1 September 1971
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 55 (5) , 2279-2289
- https://doi.org/10.1063/1.1676406
Abstract
It has been shown by the method of statistical mechanics that the existing first approximation to the regular solutions is incorrect. The correct approximation has been obtained by finding the distribution function for a given number of bonds between the unlike molecules in solution. Equations have been derived to represent the excess Gibbs energy (Gibbs free energy), enthalpy, and entropy of mixing of binary systems. Calculated and experimental results are compared to show the usefulness of derived equations.Keywords
This publication has 2 references indexed in Scilit:
- Statistical theory of superlatticesProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1935
- Beitrag zur Theorie des FerromagnetismusZeitschrift für Physik, 1925