Palladium-complex-promoted asymmetric Diels–Alder reaction: stereoselective synthesis of a new sulfinyl-substituted phosphine ligand containing three carbon, one phosphorus and one sulfur stereogenic centres
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 1747-1748
- https://doi.org/10.1039/c39950001747
Abstract
Palladium(II) complexes derived from the optically active forms of N,N-dimethyl-1-(1-naphthyl)ethylamine are efficient promoters for the asymmetric Diels–Alder reaction between 1-phenyl-3, 4-dimethylphosphole and divinyl sulfoxide; the absolute configurations of the five newly generated chiral centres in this cycloaddition reaction were determined by a crystal structural analysis of a product complex.Keywords
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