Electropolymeric materials incorporating subsite structures related to iron-only hydrogenase: active ester functionalised poly(pyrroles) for covalent binding of {2Fe3S}-carbonyl/cyanide assemblies
- 1 January 2007
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 15,p. 1535-7
- https://doi.org/10.1039/b617399c
Abstract
We report the assembly of the first electropolymeric materials incorporating catalytic diiron subsites related to those of the iron-only hydrogenases.Keywords
This publication has 17 references indexed in Scilit:
- A novel {Fei–Feii–Feii–Fei} iron thiolate carbonyl assembly which electrocatalyses hydrogen evolutionChemical Communications, 2004
- The Hydrophilic Phosphatriazaadamantane Ligand in the Development of H2 Production Electrocatalysts: Iron Hydrogenase Model ComplexesJournal of the American Chemical Society, 2004
- All-iron hydrogenase: synthesis, structure and properties of {2Fe3S}-assemblies related to the di-iron sub-site of the H-clusterElectronic supplementary information (ESI) available: crystal and structure refinement data for complexes 4a, 4b and 5a. See http://www.rsc.org/suppdata/dt/b2/b209690k/Dalton Transactions, 2003
- The Di-Iron Subsite of All-Iron Hydrogenase: Mechanism of Cyanation of a Synthetic {2Fe3S}–Carbonyl AssemblyChemistry – A European Journal, 2002
- {2Fe3S} clusters related to the di-iron sub-site of the H-centre of all-iron hydrogenasesChemical Communications, 2001
- Synthesis of N-derivatised pyrroles: precursors to highly functionalised electropolymersJournal of the Chemical Society, Perkin Transactions 1, 1999
- Bioinorganic reaction centres on electrodes. Modified electrodes possessing amino acid, peptide and ferredoxin-type groups on a poly(pyrrole) backboneJ. Chem. Soc., Dalton Trans., 1994
- Iron–sulfur clusters in ionic polymers on electrodesJ. Chem. Soc., Dalton Trans., 1993
- Synthesis and anodic polymerisation of an L-cystine derivatised pyrrole; copolymerisation with a tetraalkylammonium pyrrole allows reduction of the cystinyl film to a cysteinyl state that binds electroactive {Fe4S4}2+ centresJournal of the Chemical Society, Chemical Communications, 1992
- Iron–sulphur clusters in ionic polymers on electrodesJournal of the Chemical Society, Chemical Communications, 1989