Extended diffusion of rigid asymmetric molecules

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Abstract
The extended diffusion theory of molecular motions in fluids has been applied to the case of rigid asymmetric molecules. Illustrative calculations of the second rank reorientational correlation time matrix and the correlation factors associated with NMR spin‐rotation relaxation are presented as functions of the angular momentumcorrelation time. Analytic expressions for these correlation times and factors in the diffusion limit are also given.