Die Kristallstruktur yon RbGeCl3 / The Crystal Structure of RbGeCl3
Open Access
- 1 April 1978
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 33 (4) , 366-369
- https://doi.org/10.1515/znb-1978-0403
Abstract
RbGeCl3 is prepared from RbCl and Ge(II) in 6 N HCl or by reaction of RbCl with HGeCl3. The compound crystallizes monoclinic, space group P21/m, with a = 798.8, b = 694.1, c = 580.0 pm, β = 106.34° and Z = 2. The crystal structure has been determined by SHELX and refined till R = 0.067. RbGeCl3 is built up by Rb+ and pyramidal GeCl3−-units. The coordination of Ge and the anionic framework is discussed.Keywords
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