Large-scale and low-cost synthesis of single-walled carbon nanotubes by the catalytic pyrolysis of hydrocarbons

Rope-like bundles of single-walled carbon nanotubes (SWNTs) similar to those obtained by laser vaporization and electric-arc techniques were synthesized on a relatively large scale and at low cost by the catalytic decomposition of hydrocarbons at a temperature of about $\text{1200\hspace{0.17em}°}\mathrm{C}$ using an improved floating catalyst method. The SWNTs thus obtained have larger diameters and are self-organized into ropes. The addition of thiophene was found to be effective in promoting the growth of SWNTs and in increasing the yield of either SWNTs or multiwalled carbon nanotubes under different growth conditions.