ORBITAL COMPLEMENTARY AND COUNTERCOMPLEMENTARY EFFECTS IN SUPEREXCHANGE INTERACTION THROUGH HETEROBRIDGES IN BINUCLEAR COPPER(II) COMPLEXES

5 May 1985

journal article
research article
Published by Oxford University Press (OUP) in Chemistry Letters

Vol. 14 (5) , 631-634
https://doi.org/10.1246/cl.1985.631

Abstract

Low antiferromagnetism of μ-alkoxo-μ-carboxylatodicopper(II) complexes were reasonably explained in terms of the orbital countercomplementary effect based on Hoffmann’s theory for superexchange interaction.

Keywords

COUNTERCOMPLEMENTARY EFFECT
ANTIFERROMAGNETISM
HETEROBRIDGES
CARBOXYLATODICOPPER
ALKOXO
BINUCLEAR
HOFFMANN

This publication has 2 references indexed in Scilit:

Copper(II) hemocyanin models
Journal of the American Chemical Society, 1981
Orbital interactions in metal dimer complexes
Journal of the American Chemical Society, 1975