STEREOSELECTIVE PREFERENCE OF BOVINE SERUM ALBUMIN IN THE BURST PHASE OF REACTION WITH AMINO ACID p-NITROPHENYL ESTERS
- 5 February 1986
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 15 (2) , 229-232
- https://doi.org/10.1246/cl.1986.229
Abstract
Bovine serum albumin exhibits remarkable acylation efficiency and stereoselectivity in the hydrolysis of optically active amino acid p-nitrophenyl esters. A stereoselective ratio, kD/kL = 66 has been observed with added Triton-x. The hydrolysis rate and stereoselectivity depend on the structure of the substrate and of added surfactants.Keywords
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