Pyrolysis of 4-chlorobut-1-ene
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 2058-2059
- https://doi.org/10.1039/j19700002058
Abstract
The thermal decomposition of 4-chlorobut-1-ene has been studied between 374 and 424 °C in a static apparatus seasoned with allyl bromide. The pyrolysis was found to be of the first order in the initial stages of the reaction and independent of initial pressure. The first-order rate constant for the reaction CH2:CH·CH·CH2Cl → CH2:CH·CH:CH2+ HCl was given by log k(sec.–1)=(13·65 ± 0·35)–(55,000 ± 1100)/4·575T.Keywords
This publication has 0 references indexed in Scilit: