New Porphyrin-Based Metal−Organic Framework with High Porosity: 2-D Infinite 22.2-Å Square-Grid Coordination Network
- 6 September 2006
- journal article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 45 (20) , 7988-7990
- https://doi.org/10.1021/ic060358h
Abstract
A new 2-D coordination network with 22.2-A square-grid coordination networks was prepared from a dicopper(II) tetraacetate [Cu2(AcO)4] as a linear linker motif and 5,10,15,20-tetra-4-pyridyl-21H,23H-porphine (H2TPyP) as a four-connected vertex, forming a regular high-porous structure. The characterization by N2 adsorption indicated that this coordination network has uniform micropores and gas adsorption cavities.Keywords
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