Anisotropic Proton Hyperfine Interaction in the CH Bond
- 1 October 1964
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 41 (7) , 2084-2087
- https://doi.org/10.1063/1.1726209
Abstract
The anisotropic proton hyperfine interaction of the CH fragment is investigated in connection with the properties of the CH bond in aromatic hydrocarbon radicals or ions by the use of the LCAO—MO's determined by the condition of minimum energy. The dependence of the hfs on the bond angle is not as great as that expected from a simple consideration of the s—p hybridizations in the CH bond.This publication has 7 references indexed in Scilit:
- Isotropic Proton Hyperfine Interaction and Properties of the CH BondThe Journal of Chemical Physics, 1963
- Electron-Spin Density in Irradiated Oriented PolyethyleneThe Journal of Chemical Physics, 1963
- Evaluation of Molecular Integrals by Solid Spherical Harmonic ExpansionsThe Journal of Chemical Physics, 1962
- The coupling between an unpaired electron spin and a proton two bonds awayMolecular Physics, 1962
- Radiation Damage in Organic Crystals. I. CH(COOH)2 in Malonic Acid1Journal of the American Chemical Society, 1960
- Theory of anisotropic hyperfine interactions inπ-electron radicalsMolecular Physics, 1959
- The evaluation of integrals occurring in the theory of molecular structure. Parts I & IIPhilosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences, 1951