Complexes of rhenium-(IV) and -(V) with ligands containing group VIB atoms

Abstract
Complexes of the type ReX4L2 and ReOX3L2(X = Cl or Br; L = tetrahydrofuran, 1,4-dioxan, 1,4-thioxan and 1,4-dithian) have been prepared. Far-i.r. and H n.m.r. measurements were used to assign the stereochemistry, and in the case of the 1,4-thioxan complexes, sulphur-to-rhenium bonding has been established.

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