Redox-active crown ethers: transmission of cation binding to a redox centre via a conjugated link
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 1122-1124
- https://doi.org/10.1039/c39870001122
Abstract
The binding of Li+ to aza-15-crown-5-linked ferrocenes results in a shift of the ferrocene oxidation wave to more positive potentials when a conjugated link exists between the azacrown nitrogen atom and the redox centre.Keywords
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