Explanation of the Anomalous Hypersensitive ${}^{3}H_{4} \to {}^{3}P_{2}$ Transition in $\Pr^{3 +}$

Publisher Website

15 September 1980

journal article
research article
Published by American Physical Society (APS) in Physical Review Letters

Vol. 45 (11) , 890-893
https://doi.org/10.1103/physrevlett.45.890

Abstract

The "pseudo-multipolar field," proposed by Jørgensen and Judd to account for hypersensitivity, is here applied to the

{}^{3}H_{4} \to {}^{3}P_{2}

transition of

\Pr^{3 +}

. It is shown that the

2^{6}

- and especially the

2^{4}

-polar components give remarkable contributions, and cannot be neglected as has been done.

Keywords

This publication has 14 references indexed in Scilit:

The intensities of lanthanide f ↔ f transitions
Published by Springer Nature ,2007
Some theoretical investigations in crystal field theory
Molecular Physics, 1979
Ionic transitions hypersensitive to environment
The Journal of Chemical Physics, 1979
Dynamic coupling contributions to the intensity of hypersensitive lanthanide transitions
Chemical Physics Letters, 1974
Hypersensitivity of spectral bands in complexes of praesodymium(III)
Chemical Physics Letters, 1970
Environmental Effects on f–f Transitions. II. “Hypersensitivity” in Some Complexes of Trivalent Neodymium
The Journal of Chemical Physics, 1968
Absorption Spectra of Gaseous NdBr3 and NdI3
The Journal of Chemical Physics, 1966
Hypersensitive pseudoquadrupole transitions in lanthanides
Molecular Physics, 1964
Angular Momentum in Quantum Mechanics
Published by Walter de Gruyter GmbH ,1957
Theory of Complex Spectra. II
Physical Review B, 1942