Heteropoly Complexes Containing Titanium II. Synthesis and Characterization of Titanotungstocobaltates
- 1 February 1997
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 27 (2) , 239-250
- https://doi.org/10.1080/00945719708000149
Abstract
New complexes, M6H2[Co II W11TiO40].xH2O (M = K, x = 12; M = (CH3)4N, x = 4), [(CH3)4N]5H2[Co IIIW11 Tio40].6H2O and [(CH3)4N]/H[Co IIW11 (TiO2)O39].4H2O, have been synthesized and characterized by elemental analysis, IR, UV-Vis and ESR spectroscopy and X-ray photoelectronic spectroscopy. The results show that the three anions have Keggin structure. Their redox property was also examined.Keywords
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