The far infrared spectra of tetrahalogenozincate(II) complexes with mixed halide ligands

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Abstract
The far infrared spectra (400-40 cm-1) of the complexes (MePh3As)2 ZnBrnCl4-n (n = 0, 1, 2, 3, or 4), (Et4N)2ZnBrnCl4-n (n = 1, 2, or 3), (Me4N)2ZnBr2Cl2, (pyH)2ZnBr2Cl2, (Et4N)2ZnBrnI4-n (n = 0, 1, 2, 3, or 4), and (Et4N)2ZnClnI4-n (n = 1 or 2) have been recorded. Vibrational assignments have been made for the zinc-halogen frequencies and the spectra are discussed in terms of known or probable structures.

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