Alkylation and the Knoevenagel Condensation of Nitrobenzylic Sulfones and Nitriles.1
- 1 March 1986
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 16 (4) , 419-423
- https://doi.org/10.1080/00397918608057717
Abstract
Nitrobenzylic sulfones and nitriles easily available via the vicarious nucleophilic substitution of hydrogen are readily alkylated in the catalytic two-phase systems, the latter enter also the Knoevenagel condensation with aldehydes.Keywords
This publication has 5 references indexed in Scilit:
- Reactions of organic anions. Part 109. Vicarious nucleophilic substitution of hydrogen in nitroarenes with carbanions of .alpha.-haloalkyl phenyl sulfonesThe Journal of Organic Chemistry, 1984
- Reactions of organic anions. Part 110. Vicarious nucleophilic substitution of hydrogen in nitroarenes with .alpha.-substituted nitriles and esters. Direct .alpha.-cyanoalkylation and .alpha.-carbalkoxyalkylation of nitroarenesThe Journal of Organic Chemistry, 1984
- VICARIOUS NUCLEOPHILIC SUBSTITUTION OF HYDROGEN. A NEW METHOD OF NUCLEOPHILIC ALKYLATION OF NITROARENESPublished by Elsevier ,1983
- Reactions of organic anions. 86. Sodium and potassium carbonates: efficient strong bases in solid-liquid two-phase systemsThe Journal of Organic Chemistry, 1978
- “Vicarious” nucleophilic substitution of hydrogen in aromatic nitro compoundsTetrahedron Letters, 1978