Penicillin biosynthesis: conversion of deuteriated (L-α-amino-δ-adipyl)-L-cysteinyl-D-valine into isopenicillin N by a cell-free extract of Cephalosporium acremonium
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 246-247
- https://doi.org/10.1039/c39810000246
Abstract
The tripeptide (L-α-amino-δ-adipyl)-L-cysteinyl-D-[22H, Me2 –2H6]valine was converted into isopenicillin N by a cell-free extract ofCephalosporium acremonium;; complete retention of all deutrons was confirmed by 2H n.m.r. spectroscopyKeywords
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