Laser-induced-fluorescence study of the reaction of N2O with hot hydrogen atoms from 248 nm excimer laser photolysis of HIa)
- 1 March 1985
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 82 (5) , 2295-2299
- https://doi.org/10.1063/1.448324
Abstract
The reaction of hot hydrogen atoms with N2O to form OH and N2 has been studied. The hot hydrogen atoms were generated by the photolysis of HI at 248 nm which produces a bimodal distribution of hydrogen atoms having 43.6 and 22.0 kcal/mol of translational energy. The OH produced was monitored by laser‐induced fluorescence in the ÖX̃ transition [(0,0) band]. The nascent rotational distribution of this hot reaction was found to be characterized by a Boltzman temperature of 4700±300 K.Keywords
This publication has 21 references indexed in Scilit:
- Hot atom-laser induced fluorescence experiments on the reaction of H(2S) with O2The Journal of Chemical Physics, 1984
- Hot-atom—laser-induced-fluorescence experiments on the reaction of H(2S) with CO2Chemical Physics Letters, 1984
- Vibrational state distributions and absolute excitation efficiencies for T-V transfer collisions of NO and CO with H atoms produced by excimer laser photolysisThe Journal of Chemical Physics, 1983
- Laser-induced fluorescence detection of OH produced by reaction of hot H atoms with CO2Chemical Physics Letters, 1983
- Measurement of the relative populations of I(2P01/2) and I(2P03/2) by laser induced vacuum ultraviolet fluorescenceThe Journal of Chemical Physics, 1983
- Laser Stimulation and Observation of Elementary Chemical Reactions in the Gas PhaseLaser Chemistry, 1983
- Evidence for high rotational excitation in CO produced by collisions with hot H atoms formed in the photodissociation of HBrThe Journal of Chemical Physics, 1982
- Vibrattonal excitation of molecules by collisions with “hot” hydrogen atoms from laser photolysisChemical Physics Letters, 1981
- Molecular beam-laser induced fluorescence studies on the chemical reactions H+NO2→OH+NO and H+ClO2→OH+ClOThe Journal of Chemical Physics, 1978
- Laser-induced fluorescence determination of internal-state distribution of OH produced by H+NO2 in crossed molecular beamsThe Journal of Chemical Physics, 1976