α-Sulfinyl Substituted Radicals; II. Stereoselective Inter- and Intramolecular Addition Reactions of Acyclic α-Sulfinyl Radicals1
- 1 January 1993
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1993 (11) , 871-874
- https://doi.org/10.1055/s-1993-22638
Abstract
Acyclic α-sulfinyl radicals exhibit high diastereoselectivity in intermolecular as well as interamolecular addition reactions to C=C double bonds. Hydroxylic solvents such as alcohols cause either a loss of diastereoselectivity or have a minor effect as observed in the latter case.Keywords
This publication has 0 references indexed in Scilit: