Formation of (Z)-allylboronates via ruthenium-catalysed hydroboration of propargyl ethers with pinacolborane
- 1 March 2002
- journal article
- research article
- Published by SAGE Publications in Journal of Chemical Research
- Vol. 2002 (3) , 142-143
- https://doi.org/10.3184/030823402103171438
Abstract
Hydroboration of propargyl ethers with pinacolborane in the presence of a catalytic amount of RuHCl(CO)(PPh3)3 involved a carbon-carbon double bond isomerisation to afford γ-alkoxyallylboronate, predominantly in the Z form, in good yields.Keywords
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